Answer:
The figures and parameters to answer this question are not clearly stated, so I will answer it in the closest best way I can.
Explanation:
Molality of alanine = mole / weight of solvent( kg)
= (170×1000)/(89×600)
= 3.18 molal
We know ∆ Tf = Kf × m
Kf = ∆ Tf / molality
= 7.9/3.18 = 2.48 °c.kg.mol-1
Now using the value of cryoscopic constant we calculate can't Hoff factor for Ammonium chloride.
i = ∆ Tf /( Kf × molality of NH4Cl)
= (24.7 × 53.5 × 600) /(2.48 × 170 × 1000)
= 1.8
How is energy or particles released from a nucleus?
Answer: The decay energy is the energy released by a radioactive decay. Radioactive decay is the process in which an unstable atomic nucleus loses energy by emitting ionizing particles and radiation.
Make the appropriate conclusion. Choose the correct answer below. A. Reject Upper H 0. There is insufficient evidence to indicate blood lactate level is linearly related to perceived recovery at alphaequals0.10. B. Reject Upper H 0. There is sufficient evidence to indicate blood lactate level is linearly related to perceived recovery at alphaequals0.10. C. Do not reject Upper H 0. There is sufficient evidence to indicate blood lactate level is linearly related to perceived recovery at alphaequals0.10. D. Do not reject Upper H 0. There is insufficient evidence to indicate blood lactate level is linearly related to perceived recovery at alphaequals0.10.
Answer:
A. Reject Upper H 0. There is sufficient evidence to conclude that a higher proportion of subjects in group 1 experienced drowsiness as a side effect than subjects in group 2 at the alphaequals0.10 level of significance.
Explanation:
H0: p1 = p2
Ha: p1 > p2
pcap = (101 + 72)/(489 + 625) = 0.1553
SE = sqrt(0.1553*(1-0.1553)*(1/489 + 1/625)) = 0.0219
Test statistic,
z = (101/489 - 72/625)/0.0219 = 4.1710
p-value = 0.0000
Reject H0
A. Reject Upper H 0. There is sufficient evidence to conclude that a higher proportion of subjects in group 1 experienced drowsiness as a side effect than subjects in group 2 at the alphaequals0.10 level of significance.
Since the hybridization of the central atom is usually the only factor needed to determine molecular shape, you can simplify by considering only the hybridization of the central atom. Using this simplified method, the O atom of CO2 would bond with one of its p or s orbitals. Use valence bond theory to devise a hybridization and bonding scheme for CO2.
Answer:
CO2 contains sp hybridized carbon and sp2 oxygen atoms (linear shape)
Explanation:
There are two sigma bonds and two pi binds in the CO2 molecule. Carbon in its ground state contains one outer 2s orbital filled with two electrons and two outer 2p orbitals which are singly filled. Oxygen contains in its ground state contains an outer 2s orbital and three 2p orbitals filled with four electrons.
When these orbitals on oxygen are sp2 hybridized, one orbital is left unhybridized in each oxygen atom. Recall that two hybrized sp2 orbitals on oxygen atom accommodate the two lone pairs and one sp2 hybridized orbital in each oxygen atom forms a sigma bond to carbon. The remaining unhybridized orbital on oxygen is used by each oxygen atom to overlap with each unhybridized p orbital on the sp hybridized carbon.
Carbon forms two sigma bonds to oxygen via the two hybridized sp orbitals on carbon. The two unhybridized orbitals overlap sideways and firm pi bonds with oxygen p orbitals.
Triatomic molecules must be either linear or bent. In CO2, the bond angle must be 180° giving a linear molecule.
The carbon atom in CO₂ has sp hybridization due to its two regions of high electron density. Each of these forms a sigma bond with an oxygen atom, resulting in a linear geometry. Each C-O bond consists of one sigma bond and one pi bond, forming double bonds.
Explanation:The question asks for a hybridization and bonding scheme for the molecule CO₂ based on the valence bond theory. In CO₂, the central atom is Carbon (C). This atom is surrounded by two regions of high electron density, each represented by the double bonds with oxygen atoms.
According to the valence bond theory, a central atom with two regions of electron density (Lone pairs or bonds) is associated with sp hybridization. Therefore, in the case of CO₂, the Carbon atom will have sp hybridization. Since sp hybridization generates two hybrid orbitals, each of these will form a σ (sigma) bond with one of the Oxygen atoms maintaining a linear geometry (180° angle).
Moving onto the molecule's bond character, each C-O bond in CO₂ is a double bond, consisting of a σ bond and a π bond. The σ bonds are formed by the overlapping of sp hybrid orbitals of carbon with p orbitals of oxygen, while the π bonds are formed by the side-by-side overlapping of unhybridized p orbitals from both Carbon and Oxygen atoms.
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_ H₂ + O2
H20
balance equation
Answer:
2H2 + O2 = 2H2O
Explanation:
From the original equation, you first need to write each component separately.
Left side: H = 2 ; O = 2 (number based on the subscript)
Right side: H = 2 ; O = 1 (number based on the subscripts; no subscript means that the element is just 1)
Notice that the number of H is already balance but the number of O is not. In order to balance the O, you need to multiply the element by 2, but you CANNOT do this by simply changing the subscript.
Left side: H = 2 ; O = 2
Right side: H = 2 x 2 = 4 ; O = 1 x 2 = 2
Now, notice that the number of O is now balance (both are 2) but the number of H is not (since
You also multiply the left side H by 2. Hence,
Left side: H = 2 x 2 = 4 ; O = 2
Right side: H = 2 x 2 = 4 ; O = 1 x 2 = 2
The equation is now balanced.
a. What is the Gibbs free energy for this reaction at 298 K?
2NH3(g) N2(g) + 3H2(g)
ΔH = 91.8 kJ
ΔS = 0.1987 kJ/K
Is the reaction spontaneous at 298 K (room temperature)? (3 points)
Answer:
32.6 Jmol-1
Explanation:
Now we have to use the formula
∆G= ∆H-T∆S where
∆G= change in free energy (the unknown)
∆H= enthalpy change = 91.8KJ
∆S= entropy change= 0.1987 kJ/K
T= temperature= 298K
∆G= 91.8 - (298× 0.1987)
∆G= 91.8 - 59.2126
∆G= 32.6 Jmol-1
Answer:
the reaction is spontaneous
Explanation:
The addition of 9.54 kJ of heat is required to raise the temperature of 225.0 g of a liquid hydrocarbon from 20.5 degree C to 45.0 degree C. What is the heat capacity of this hydrocarbon?
The heat capacity of the hydrocarbon is 0.389 kJ/°C.
Explanation:To find the heat capacity of the hydrocarbon, we can use the formula:
Heat Capacity = q / ∆T
where q is the heat added and ∆T is the change in temperature.
Given that q = 9.54 kJ and ∆T = 45.0 °C - 20.5 °C = 24.5 °C, we can plug these values into the formula:
Heat Capacity = 9.54 kJ / 24.5 °C = 0.389 kJ/°C
Therefore, the heat capacity of the hydrocarbon is 0.389 kJ/°C.
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Write the chemical reaction for nitrous acid in water, whose equilibrium constant is K a . Include the physical states for each species. K a reaction: Write the chemical reaction for the nitrite ion in water, whose equilibrium constant is K b . Include the physical states for each species.
Answer:
HNO₂(aq) + H₂O(l) ⇄ NO₂⁻(aq) + H₃O⁺
NO₂⁻(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq)
Explanation:
According to Brönsted-Lowry acid-base theory, nitrous acid is an acid because it transfers an H⁺ to another compound. The corresponding reaction is:
HNO₂(aq) + H₂O(l) ⇄ NO₂⁻(aq) + H₃O⁺
According to Brönsted-Lowry acid-base theory, nitrite ion is a base because it accepts an H⁺ from another compound. The corresponding reaction is:
NO₂⁻(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq)
The chemical reaction for nitrous acid in water is HNO₂(aq) + H₂O(l) ⇄ NO₂⁻(aq) + H₃O⁺
And, the chemical reaction for the nitrite ion in water, is
NO₂⁻(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq)
Brönsted-Lowry acid-base theory:
Since nitrous acid should be an acid due to this it transferred an H⁺ to another compound so here the reaction should be HNO₂(aq) + H₂O(l) ⇄ NO₂⁻(aq) + H₃O⁺
Here nitrite ion should have a base due to this, it accepts an H⁺ from another compound. So here the reaction is NO₂⁻(aq) + H₂O(l) ⇄ HNO₂(aq) + OH⁻(aq)
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EDTA EDTA is a hexaprotic system with the p K a pKa values: p K a1 = 0.00 pKa1=0.00 , p K a2 = 1.50 pKa2=1.50 , p K a3 = 2.00 pKa3=2.00 , p K a4 = 2.69 pKa4=2.69 , p K a5 = 6.13 pKa5=6.13 , and p K a6 = 10.37 pKa6=10.37 . The distribution of the various protonated forms of EDTA will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA EDTA , it is convenient to calculate the fraction of EDTA EDTA that is in the completely unprotonated form, Y 4 − Y4− . This fraction is designated α Y 4 − αY4− . Calculate α Y 4 − αY4− at two pH values.
To calculate αY4-, we need to find the fraction of EDTA in its protonated forms at the given pH and divide the concentration of the completely unprotonated form by the total concentration of EDTA.
Explanation:To calculate the fraction of EDTA that is in the completely unprotonated form, Y4- (designated as αY4-), at a given pH value, we need to find the values of αY4- at two different pH values.
To calculate αY4-, we first need to find the fraction of EDTA in its protonated forms at the given pH.
For example, at pH = 2, we can calculate the fractional composition of each protonated form by dividing the concentration of the protonated form by the total concentration of all protonation states of EDTA. We can repeat this calculation for another pH value to find αY4- at that pH.
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The fraction of EDTA in the completely unprotonated form at pH3 is approximately [tex]\( 9.28 \times 10^{-4} \)[/tex], and at pH8 is approximately [tex]\( 8.83 \times 10^{-7} \)[/tex].
To calculate the fraction of EDTA that is in the completely unprotonated form, [tex]\( \alpha_{Y^{4-}} \)[/tex], at a given pH, we use the following equation:
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + \sum_{i=1}^{6} 10^{(pH - pKa_i)}} \][/tex]
Here, [tex]\( pKa_i \)[/tex] represents the [tex]\( i \)-th[/tex] acid dissociation constant for EDTA. Since EDTA is a hexaprotic acid, it has six [tex]\( pKa \)[/tex] values, which are given as:
[tex]\( pKa_1 = 0.00 \), \( pKa_2 = 1.50 \), \( pKa_3 = 2.00 \), \( pKa_4 = 2.69 \), \( pKa_5 = 6.13 \), and \( pKa_6 = 10.37 \).[/tex]
Calculate [tex]\( \alpha_{Y^{4-}} \)[/tex] for two pH values, say pH = 3 and pH = 8.
For pH = 3:
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 10^{(3 - 0.00)} + 10^{(3 - 1.50)} + 10^{(3 - 2.00)} + 10^{(3 - 2.69)} + 10^{(3 - 6.13)} + 10^{(3 - 10.37)}} \][/tex]
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 10^{3} + 10^{1.5} + 10^{1} + 10^{0.31} + 10^{-3.13} + 10^{-7.37}} \][/tex]
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 1000 + 31.62 + 10 + 2.08 + 0.00074 + 4.17 \times 10^{-8}} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx \frac{1}{1 + 1000 + 31.62 + 10 + 2.08} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx \frac{1}{1033.62 + 31.62 + 10 + 2.08} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx \frac{1}{1077.32} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx 9.28 \times 10^{-4} \][/tex]
For pH = 8:
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 10^{(8 - 0.00)} + 10^{(8 - 1.50)} + 10^{(8 - 2.00)} + 10^{(8 - 2.69)} + 10^{(8 - 6.13)} + 10^{(8 - 10.37)}} \][/tex]
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 10^{8} + 10^{6.5} + 10^{6} + 10^{5.31} + 10^{1.87} + 10^{-2.37}} \][/tex]
[tex]\[ \alpha_{Y^{4-}} = \frac{1}{1 + 10000000 + 316227.76 + 1000000 + 20794.42 + 74.12 + 0.00417} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx \frac{1}{10000000 + 316227.76 + 1000000 + 20794.42 + 74.12} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx \frac{1}{1131992.3} \][/tex]
[tex]\[ \alpha_{Y^{4-}} \approx 8.83 \times 10^{-7} \][/tex]
Therefore, the fraction of EDTA in the completely unprotonated form at pH 3 is approximately [tex]\( 9.28 \times 10^{-4} \)[/tex], and at pH 8 is approximately [tex]\( 8.83 \times 10^{-7} \)[/tex].
The complete question is:
EDTA is a hexaprotic system with the PK, values:
PKa1 = 0.00, pKa2 = 1.50, pKa3 2.00, pKa4 = 2.69,
pKa5 6.13, and pKa6 10.37.
The distribution of the various protonated forms of EDTA will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA, it is convenient to calculate the fraction of EDTA that is in the completely unprotonated form, Y4-. This fraction is designated αY4−. Calculate αY4− at two pH values.
pH = 3.10
pH = 10.55
Be sure to answer all parts. Calculate ΔH o for the following reaction in two ways, using the data given below. H2(g) + I2(g) → 2HI(g) (a) Using the equation ΔH o rxn = ∑(BE(reactants)) − ∑(BE(products)) kJ/mol (b) Using the equation ΔH o rxn = ∑(nΔH o f (products)) − ∑(mΔH o f (reactants)) kJ/mol Bond BE kJ/mol Substance ΔH o f kJ/mol H―H 436.4 H2(g) 0 I―I 151 I2(g) 61.0 H―I 298.3 HI(g) 25.9
Answer:
a) ΔH°rxn = -9.2kJ/mol
b) ΔH°rxn = -9.2kJ/mol
Explanation:
Using Hess's law, you can find ΔH of a reaction from ΔH of formation of the substances involved in the reaction, thus:
ΔH°rxn = ∑(BE(reactants)) − ∑(BE(products))
Or:
ΔH°rxn = ∑(nΔH°f (products)) − ∑(mΔH°f (reactants))
For the reaction:
H₂(g) + I₂(g) → 2HI(g)
a) Using the first equation:
ΔH°rxn = ΔH (H-H) + ΔH (I-I) - 2ΔHBE (H-I)
ΔH°rxn = 436.4kJ + 151kJ - 2×298.3kJ
ΔH°rxn = -9.2kJ/mol
b) Using the second equation:
ΔH°rxn = 2Δ°f (HI) − ΔH°f (H₂) - ΔH°f (I₂)
ΔH°rxn = 2×25.9kJ - 0kJ - 61.0kJ
ΔH°rxn = -9.2kJ/mol
The reaction H₂(g) + I₂(g) → 2HI(g) has a ΔHo value of -9.2 kJ/mol, which is calculated using both bond dissociation energies and enthalpies of formation. This indicates the reaction is exothermic.
Explanation:To calculate ΔHo for the reaction H₂(g) + I₂(g) → 2HI(g),first we will use the bond dissociation energies (BE), and second the enthalpies of formation (ΔHof).
(a) Using the equation ΔHorxn = ∑BE(reactants) − ∑BE(products), we get ΔHorxn = [1(436.4 kJ/mol) + 1(151 kJ/mol)] - 2(298.3 kJ/mol) = -9.2 kJ/mol. This asserts that the reaction is exothermic and energy is released in the process. The sum of bond energies of reactants is smaller than that of the products.
(b) Using the equation ΔHorxn = ∑nΔHof(products) − ∑mΔHof(reactants), we get ΔHorxn = 2(25.9 kJ/mol) - [1(0 kJ/mol) + 1(61.0 kJ/mol)] = -9.2 kJ/mol. This value is same as obtained by the first method and thus validates it.
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Question 7 When of benzamide are dissolved in of a certain mystery liquid , the freezing point of the solution is lower than the freezing point of pure . On the other hand, when of iron(III) chloride are dissolved in the same mass of , the freezing point of the solution is lower than the freezing point of pure . Calculate the van't Hoff factor for iron(III) chloride in . Be sure your answer has a unit symbol, if necessary, and round your answer to significant digits.
Answer:
See explaination
Explanation:
moles of benzamide = mass / Molar mass of it = 70.4g / ( 121.14g/mol) = 0.58 mol
Molality = moles of solute ( benzamide) / ( solvent mass in kg) = 0.58 mol / ( 0.85kg) = 0.6837
we have formula dT = i x Kf x m , where dT = change in freezing point = 2.7C , i = vantoff factor = 1 for non dissociable solutes , Kf = freezing oint constant of solvent , m = 0.6837
hence 2.7C = 1 x Kf x 0.6837m
Kf = 3.949 C/m
we use this Kf value for calculating i for NH4Cl , where moles of NH4Cl = ( 70.4g/53.491g/mol) =1.316 mol
molality = ( 1.316mol) / ( 0.85kg) = 1.5484 , dT = 9.9
hence 9.9 = i x 3.949C/m x 1.5484 m
i = 1.62
What is the molarity of a hydrochloric acid solution, HCl (aq), if 30.00 mL of the solution is required to completely react with 25.00 mL of a 0.200 M magnesium hydroxide solution, Mg(OH)2 (aq)? Be sure to write out the balanced chemical reaction between these two compounds.
Answer:
0.333 M
Explanation:
Step 1: Write the balanced equation
2 HCl(aq) + Mg(OH)₂(aq) = MgCl₂(aq) + 2 H₂O(l)
Step 2: Calculate the reacting moles of Mg(OH)₂
25.00 mL of a 0.200 M magnesium hydroxide react. The reacting moles of Mg(OH)₂ are:
[tex]25.00 \times 10^{-3} L \times \frac{0.200mol}{L} = 5.00 \times 10^{-3} mol[/tex]
Step 3: Calculate the reacting moles of HCl
The molar ratio of HCl(aq) to Mg(OH)₂ is 2:1. The reacting moles of HCl are:
[tex]5.00 \times 10^{-3} molMg(OH)_2 \times \frac{2mol}{1molMg(OH)_2} =1.00 \times 10^{-2}molHCl[/tex]
Step 4: Calculate the molarity of HCl
[tex]\frac{1.00 \times 10^{-2}mol}{30.00 \times 10^{-3}L} = 0.333 M[/tex]
is 8 inches enough to satisfy a girl
Answer:
Yes
Explanation:
2. What is the difference between a formula unit for an ionic compound and a molecular formula
for a molecule?
Final answer:
The formula unit for an ionic compound represents the simplest ratio of positive and negative ions that result in a neutral compound, typically involving metals and nonmetals. A molecular formula for a molecule indicates the actual number of atoms of each element in a molecule, formed by covalent bonds between nonmetals. The periodic table helps distinguish between the two.
Explanation:
The difference between a formula unit for an ionic compound and a molecular formula for a molecule lies in the types of elements involved and the nature of their bonding. A formula unit refers to the simplest, neutral collection of ions in an ionic compound, which is comprised of metals and nonmetals. The periodic table can be used to determine which elements fall into these categories. On the other hand, a molecular formula represents the actual number and type of atoms in a molecule, which are bonded covalently and generally involve nonmetal elements.
For ionic compounds, the formula mass is used, which is the sum of atomic masses of all the elements in the empirical formula (simplest ratio of ions), with each multiplied by its corresponding subscript. This contrasts with a molecular compound's molecular mass, which is computed using the molecular formula, representing the total mass of all atoms in the actual molecule.
To summarize, the key distinction is that molecular formulas represent covalently-bonded nonmetals and give the specific numbers and types of atoms, whereas formula units represent ionic compounds composed of metals and nonmetals and indicate the simplest ratio of ions that results in neutrality.
Consider the following reaction.
CO2(g) + H2(9)
-
CO(g) + H2O(1)
What is being oxidized?
O carbon
carbon dioxide
oxygen
o hydrogen
Answer:
Hydrogen
Explanation:
It gains oxygen from carbon dioxide to form water
Oxidation is the addition of oxygen to an element in a chemical reaction
Answer:
Its D
Explanation:
Trust me just get ronas and cheat
Consider this chemical reaction, where moving from left to right represents moving forward in time. A five panel comic strip. In the first panel, there are ten large red spheres. In the second panel, there are 8 large red spheres and two small blue spheres. In the third panel, there are six large red spheres and four small blue spheres. In the fourth panel, there are four large red spheres and six small blue spheres. In the fifth panel, there are four large red spheres and six small blue spheres. At what point does the reaction first reach equilibrium
Answer:
The reaction reaches equilibrium at the fourth panel.
Explanation:
Chemical Equilibrium is achieved when the overall properties the system seem to be constant, that is, stop changing.
Although, for chemical equilibrium, the right term for this equilibrium is dynamic equilibrium; the rate of forward reaction balances the rate of backward reaction, but concentrations can keep changing.
The point where equilibrium is achieved is when exactly when we reach the panel where the spheres that make up this panel is the same as the next panel and the next, that is, the specific colour and number of spheres start to become unchanged.
And from the description given in the question,
- In the first panel, there are ten large red spheres.
- In the second panel, there are 8 large red spheres and two small blue spheres.
- In the third panel, there are six large red spheres and four small blue spheres.
- In the fourth panel, there are four large red spheres and six small blue spheres.
- In the fifth panel, there are four large red spheres and six small blue spheres.
It is evident that the make-up of the spheres have become the same as at the fourth and fifth panel. This means that the first point where this final configuration of spheres first appeared is the fourth panel.
Hence, equilibrium is first reached at the fourth panel.
Hope this Helps!!!
The reaction reaches equilibrium at the fourth panel. A reaction is at equilibrium when the amounts of reactants or products no longer change. Chemical equilibrium is a dynamic process
What is Chemical Equilibrium?It is the rate of formation of products by the forward reaction is equal to the rate at which the products re-form reactants by the reverse reaction.
The point where equilibrium is achieved is when exactly when we reach the panel where the spheres that make up this panel is the same as the next panel and the next, that is, the specific color and number of spheres start to become unchanged.
As per the descriptions of panel given in question:
It is evident that the make-up of the spheres have become the same as at the fourth and fifth panel. This means that the first point where this final configuration of spheres first appeared is the fourth panel.
Hence, equilibrium is first reached at the fourth panel.
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Consider an electrochemical cell based on the spontaneous reaction 2AgCl(s) + Zn(s) → 2Ag(s) + 2Cl– + Zn2+. If the zinc ion concentration is kept constant at 1 M, and the chlorine ion concentration is decreased from 1 M to 0.001 M, the cell voltage should A) increase by 0.06 V. D) decrease by 0.18 V. B) increase by 0.18 V. E) increase by 0.35 V. C) decrease by 0.06 V.
Answer:
B) increase by 0.18 V
Explanation:
The given chemical spontaneous reaction is :
[tex]2 AgCl_{(s)} + Zn _{(s)} \to 2Ag (s) + 2Cl^- _{(aq)} + Zn ^{2+} _{(aq)}[/tex]
By applying Nernst Equation:
[tex]E_{cell} = E^0 - \frac{0.059}{n} log [\frac{product}{reactant}][/tex]
here ;
n = number of electrons transferred in the reaction
n =2
[tex]E^0 = E^0_{cathode } - E^0_{anode}[/tex]
[tex]E^0 = E^0_{Ag^+/Ag } - E^0_{Zn^{2+}/Zn}[/tex]
[tex]E^0 =+0.80 \ V -(-0.76 \ V)[/tex]
[tex]E^0 =1.56 \ V[/tex]
When it happens to occur that the concentration of chlorine (aq) and Zn²⁺ (aq) is 1 M ;
[tex]E^0_{cell} = E^0[/tex] is as follows:
[tex]E_{cell} = E^0 - \frac{0.059}{n} log [\frac{product}{reactant}][/tex]
[tex]E_{cell} = 1.56 - \frac{0.059}{n} log [\frac{[Zn^{2+}]}{[Cl^-]^2}][/tex]
[tex]E_{cell} = 1.56 - \frac{0.059}{n} log (1) \ \ \ \ \ \ \ ( where \ log (1) = 0)[/tex]
[tex]E_{cell} = 1.56 \ V[/tex]
Now; the [tex]E_{cell}[/tex] value in the decreased concentration of chlorine (aq) ion is calculated as:
[tex]E_{cell} = E^0 - \frac{0.059}{n} log [\frac{product}{reactant}][/tex]
[tex]E_{cell} = 1.56 - \frac{0.059}{n} log [\frac{[Zn^{2+}]}{[Cl^-]^2}][/tex]
[tex]E_{cell} = 1.56 - \frac{0.059}{n} log (1*0.001^2)[/tex]
[tex]E_{cell} = +1.737 \ V[/tex]
Hence; the change in voltage = [tex]E_{cell} - E^0[/tex]
= 1.737 - 1.56
= 0.177 V
≅ 0.18 V
We therefore conclude that: since the [tex]E^0_{cell}[/tex] value after the decreased concentration of Chlorine is greater than the [tex]E^0[/tex] before the change; then there is increase in the value by 0.18 V
Acid chlorides can be converted into primary amines with the loss of a single carbon atom via the Curtius rearrangement. The reaction involves treating an acid chloride with sodium azide to form an acyl azide. The acyl azide then loses N2 to give an isocyanate, which is hydrolyzed to release CO2 and the primary amine. Draw curved arrows to show the movement of electrons in this step of the mechanism.
Answer:
Find the given attachment.
In addition to displacing halide ions, the acetylide ion also adds to carbonyl groups. 2-Methyl-3-butyn-2-ol (MBI) is an acetylenic alcohol used in the manufacture of products for the agrochemical and specialty chemical industry. It can be synthesized by the addition of acetylene to acetone to form the alkoxide ion and, as a second step, protonation of the alkoxide ion to produce the alcohol. Complete the mechanism for 2-methyl-3-butyn-2-ol production by drawing in the products of each step and the missing curved arrows. Sodium amide deprotonates the terminal alkyne to form sodium ethynide. Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges where needed. Electron flow arrows should start on an atom or a bond and should end on an atom, bond, or location where a new bond should be create
Answer:
Explanation:
check below for explanation.
20.0 g of Nitrogen is produced when oxygen gas reacts with NO gas. 29.8 L of oxygen is required at STP to produce this 20.0 g of NO. A.yes B.false
Answer:
There will be produced 30.64 grams of nitrogen dioxide
The statement is false
Explanation:
Step 1: Data given
MAss of nitrogen produced = 20.0 grams
Molar mass of N2 = 28.0 g/mol
Mass of NO = 20.0 grams
Molar mass of NO = 30.01 g/mol
Volume of O2 at STP = 29.8 L
Step 2: the balanced equation
2NO + O2 → 2N02
Step 3: Calculate moles NO
Moles NO = mass NO / molar mas NO
Moles NO = 20.0 grams / 30.01 g/mol
Moles NO = 0.666 moles
Step 4: Calculate moles O2
1 mol O2 at STP = 22.4 L
29.8 L = 29.8/22.4 = 1.33 moles
Step 5: Calculate the limiting reactant
For 2 moles NO we need 1 mol O2 to produce 2 moles NO2
NO is the limiting reactant. IT will completely be consumed (0.666 moles).
O2 is in excess. There will react 0.666/2 = 0.333 moles O2
There will remain 1.333 - 0.333 = 0.997 moles O2
Step 6: Calculate moles NO2
For 2 moles NO we need 1 mol O2 to produce 2 moles NO2
For 0.666 moles NO we'll have 0.666 moles NO2
Step 7: Calculate mass NO2
Mass NO2 = moles NO2 * molar mass NO2
Mass NO2 = 0.666 moles * 46.0 g/mol
Mass NO2 = 30.64 grams
There will be produced 30.64 grams of nitrogen dioxide
The statement is false
a student prepares a dilute solution of sodium hydroxidem, NaOH (aq), starting with 6 M sodium hydroxide. She then titrates a 1.372 g samle of KHP with the dilute sodium hydroxide solution, NaOH (aq), calculate the molar concentration of the sodium hydroxide solution, NAoH (aq)
Answer:
M = 0.3077 M
Explanation:
As I said in the comments, you are missing the required volume of the base to react with the KHP. I found this on another site, and the volume it used was 21.84 mL.
Now, KHP is a compound often used to standarize NaOH or KOH solutions. This is because it contains a mole ratio of 1:1 with the base, so it's pretty easy to use and standarize any base.
Now, as we are using an acid base titration, the general expression to use when a acid base titration reach the equivalence point would be:
n₁ = n₂ (1)
This, of course, if the mole ratio is 1:1. In the case of KHP and NaOH it is.
Now, we also know that moles can be expressed like this:
n = M * V (2)
And according to this, we are given the volume of base and the required mass of KHP. So, if we want to know the concentration of the base, we need to get the moles of the KHP, because in the equivalence point, these moles are the same moles of base.
The reported molar mass of KHP is 204.22 g/mol, so the moles are:
n = 1.372 / 204.22 = 6.72x10⁻³ moles
Now, we will use expression (2) to get the concentration of the diluted base:
n = M * V
M = n / V
M = 6.72x10⁻³ / 0.02184
M NaOH = 0.3077 M
This is the concentration of the dilute solution of NaOH
The molar concentration of sodium hydroxide ( NaOH ) is ; 0.3077 M
Given data :
Volume of base = 21.84 mL = 0.02184 L ( missing data )
Molar mass of KHP = 204.22 g/mol
mass of KHP = 1.372 g
At equivalence point
n1 = n2 ( ratio of KHP to NaOH )
note : n = M * V ---- ( 1 )
First step : calculate the number of moles of KHP
n = mass / molar mass
n = 1.372 / 204.22 = 6.72 * 10⁻³ moles
Determine the molar concentration of NaOH
From equation ( 2 )
M ( molar concentration ) = n / V
= 6.72 * 10⁻³ moles / 0.02184 L
= 0.3077 M
Hence we can conclude that The molar concentration of sodium hydroxide ( NaOH ) is 0.3077 M
Learn more : https://brainly.com/question/21841645
Collagen is made of fibers and is found in tendons and cartilage. Collagen
contributes to meat toughness and is, therefore, an example of which type
of protein?
Answer:
Collagen is a "fibrous proteins" present in the extracellular matrix.
Explanation:
Protein are made up of hundreds or thousands of smaller units called amino acids and is made of carbon, hydrogen, oxygen, nitrogen and sometimes sulfur and is found in many foods. Proteins are organic molecules found in living organisms.
There are three types of proteins; fibrous, globular, and membrane.
Collagen which is a fibrous proteins, form muscle fiber, tendons, connective tissue and bone.
Collagen are naturally occurring proteins that consist of single molecules made up of amino-acids, which are in turn built of carbon, oxygen and hydrogen. It is mostly found in fibrous tissues such as tendons, ligaments, and skin.
The synthesis of collagen occurs in two stages: intracellular and extracellular.
Collagen is an abundant connective tissues such as cartilage, tendons, bones, and ligaments. Collagen is a contributing factor to variation in meat tenderness and texture.
HURRY PLS HELP PLEASE: A 40.0-L sample of fluorine is heated from 363 Kelvin to 459 K. What volume will the sample occupy at the higher temperature?
19.3 L
31.6 L
50.5 L
82.6 L
Final answer:
The volume of a 40.0-L sample of fluorine gas heated from 363 K to 459 K can be found using Charles's Law. After setting up the equation from Charles's Law and solving for the new volume (V2), we find that the volume at the higher temperature is 50.5 L.
Explanation:
To determine the new volume of fluorine gas when heated from 363 K to 459 K, we can use Charles's Law, which states that for a given mass of an ideal gas at constant pressure, the volume is directly proportional to its absolute temperature. Specifically, the formula is V1/T1 = V2/T2, where V1 is the initial volume, T1 is the initial temperature, V2 is the final volume, and T2 is the final temperature.
In this case, the initial volume (V1) is 40.0 L and the initial temperature (T1) is 363 K. The final temperature (T2) is 459 K. Plugging these values into the formula, we have:
40.0 L / 363 K = V2 / 459 K
Multiplying both sides by 459 K to solve for V2 gives us:
V2 = (40.0 L x 459 K) / 363 K
Upon calculation, V2 = 50.5 L. Therefore, the new volume occupied by the sample at 459 K is 50.5 liters.
A container of gas is heated from 250 K to 303 K. What is the new pressure if the initial pressure is 880 kPa? (Assume constant volume).
Answer:
The new pressure at constant volume is 1066.56 kPa
Explanation:
Assuming constant volume, the pressure is diectly proportional to the temperature of a gas.
Mathematically, P1/T1 = P2 /T2
P1 = 880 kPA= 880 *10^3 Pa
T1 = 250 K
T2 = 303 K
P2 =?
Substituting for P2
P2 = P1 T2/ T1
P2 = 880 kPa * 303 / 250
P2 = 266,640 kPa/ 250
P2 = 1066.56 kPa.
The new pressure of the gas is 1066.56 kPa
At constant volume, if the temperature of the container is heated to the given value, the pressure of the gas increases to 1066.5kPa.
What is Gay-Lussac's law?Gay-Lussac's law states that the pressure exerted by a given quantity of gas varies directly with the absolute temperature of the gas.
It is expressed as;
P₁/T₁ = P₂/T₂
Given the data in the question;
Initial pressure P₁ = 880kPa = ( 880 / 101.325)atm = 8.68492atmInitial temperature T₁ = 250KInitial temperature T₂ = 303KFinal pressure P₂ = ?P₁/T₁ = P₂/T₂
P₁T₂ = P₂T₁
P₂ = P₁T₂ / T₁
P₂ = (8.68492atm × 303K) / 250K
P₂ = (2631.53atmK) / 250K
P₂ = 10.526atm
P₂ = (10.526 × 101.325)kPa
P₂ = 1066.5kPa
Therefore, at constant volume, if the temperature of the container is heated to the given value, the pressure of the gas increases to 1066.5kPa.
Learn more about Gay-Lussac's law here: brainly.com/question/1358307
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Retigeranic Acid II: The Endgame. This question deals with transformations that were employed in the last few steps of a total synthesis of Retigeranic Acid. (a) Provide reagents that will accomplish the transformation of molecule 6 to molecule 7. (b) Draw the mechanism of the transformation of molecule 7 to molecule 8 when treated with sodium hydroxide in water. (It is ok to abbreviate parts of the molecule not involved in the reaction to make drawing a little easier).
Answer:
see explaination
Explanation:
Please kindly check attachment for the step by step solution of the given problem
In an isothermal gas chromatography experiment using an ECD detector, 1.69 nmols of nchlorohexane, C6H13Cl, was added as an internal standard to an unknown amount of nchlorodecane, C10H21Cl. The area of the first peak to elute was 32434 units and the area of the second peak to elute was 2022 units. Calculate the amount of chlorodecane in the unknown.
Answer:
The amount of Chlorodecane in the unknown is 0.105nmols
Explanation:
a) Since the GC is in an isothermal state, Chlorohexane C6H13Cl (1.69 nmols) because of its lower boiling point will elute first and Chlorodecane C12H21Cl will elute second.
The area of the first peak corresponding to Chlorohexane is 32434 units.
The area of the second peak corresponding to chlorodecane is 2022 units.
Since the response factor of the compound is not given in question and considering the response factor is same for both the compounds, the answer will be as follow:
1.69 nmols of Chlorohexane gives 32434 units
How much of chlorodecane gives 2022 units
By cross multiplication;
Moles of Chlorodecane = 2022*1.69/32434
=0.105nmols
A galvanic cell is powered by the following redox reaction: br2 (l) 2NO(g) (l)(aq) (aq) (aq) Answer the following questions about this cell. If you need any electrochemical data, be sure you get it from the ALEKS Data tab. Write a balanced equation for the half-reaction that takes place at the cathode. Write a balanced equation for the half-reaction that takes place at the anode. Calculate the cell voltage under standard conditions. Round your answer to decimal places.
Final answer:
In the galvanic cell, the reduction of Br₂ to 2Br⁻ occurs at the cathode, while the oxidation of 2NO to N₂O₄ occurs at the anode. The cathode is the silver electrode and the anode is the copper electrode. The silver electrode is the positive electrode and the copper electrode is the negative electrode.
Explanation:
In the galvanic cell powered by the redox reaction between Br₂ and 2NO, the half-reaction that takes place at the cathode is the reduction of Br₂ to 2Br⁻. The half-reaction that takes place at the anode is the oxidation of 2NO to N₂O₄.
For the electrode assignment, the cathode is the electrode where reduction occurs, so it is the silver electrode. The anode is the electrode where oxidation occurs, so it is the copper electrode.
The positive electrode in this galvanic cell is the cathode, which is the silver electrode, and the negative electrode is the anode, which is the copper electrode.
Determine the number of moles of H in each sample.
1). 8.48 mole NH3
2).0.111 mole N2H4
3). 36.0 mole C10 H22
Answer:
1) 25.44 moles H
2) 0.444 moles H
3) 792 moles H
Explanation:
Step 1: Number of moles H in 8.48 moles NH3
In 1 mol NH3 we have 3 moles H
For 8.48 moles NH3 we have 3*8.48 = 25.44 moles H
Step 2: Number of moles H in 0.111 moles N2H4
For 1 mol N2H4 we have 4 moles H
For 0.111 moles N2H4 we have 4*0.111 = 0.444 moles H
Step 3: Number of moles H in 36.0 moles C1OH22
For 1 mol C10H22 we have 22 moles of H
For 36.0 moles C1OH22 we have 22*36.0 = 792 moles H
To how much water should 50mL of 12M hydrochloric acid be added to produce a 4M solution?
Answer:
50 mL of 12M HCl should be added into 100 mL of water to produce a 4M solution.
Explanation:
According to law of dilution-
[tex]C_{1}V_{1}=C_{2}V_{2}[/tex]
where [tex]C_{1},C_{2},V_{1}[/tex] and [tex]V_{2}[/tex] are initial concentration, final concentration, initial volume and final volume respectively.
Here, [tex]C_{1}=12M[/tex] , [tex]C_{2}=4M[/tex] , [tex]V_{1}=50mL[/tex]
So, [tex]V_{2}=\frac{C_{1}V_{1}}{C_{2}}[/tex] = [tex]\frac{(12M)\times (50mL)}{(4M)}[/tex] = 150 mL
Hence, final volume of HCl solution should be 150 mL.
So, volume of water needed = (150-50) mL = 100 mL
Therefore 50 mL of 12M HCl should be added into 100 mL of water to produce a 4M solution.
You need to add [tex]\( {150} \)[/tex] mL of water to 50 mL of 12 M hydrochloric acid to produce a 4 M solution.
To determine how much water should be added to 50 mL of 12 M hydrochloric acid (HCl) to produce a 4 M solution, we can use the dilution formula which states:
[tex]\[ C_1V_1 = C_2V_2 \][/tex]
where:
- [tex]\( C_1 \)[/tex] and [tex]\( V_1 \)[/tex] are the concentration and volume of the initial solution (12 M and 50 mL, respectively),
- [tex]\( C_2 \)[/tex] and [tex]\( V_2 \)[/tex] are the concentration and volume of the final solution (4 M and the unknown volume of water, respectively).
Let's solve for [tex]\( V_2 \)[/tex]:
[tex]\[ C_1V_1 = C_2V_2 \][/tex]
Substitute the given values:
[tex]\[ 12 \times 50 = 4 \times V_2 \][/tex]
Solve for [tex]\( V_2 \)[/tex]:
[tex]\[ 600 = 4 \times V_2 \][/tex]
[tex]\[ V_2 = \frac{600}{4} \][/tex]
[tex]\[ V_2 = 150 \text{ mL} \][/tex]
Electrophilic addition to an alkene proceeds via Markovnikov regiochemistry due to the formation of the more stable carbocation intermediate. In the case of conjugated dienes, that is dienes that are separated by one sigma bond, the carbocation that is formed is stabilized additionally by resonance. Addition of the nucleophile to the carbocation intermediate can therefore give two types of products: direct addition to the double bond, also called 1,2-addition, and conjugate addition to the resonance stabilized carbocation, also called 1,4-addition. Allylic carbocation stability is affected by both the nature of the carbocation (primary allylic, secondary allylic, or tertiary allylic) and by the degree of substitution of the double bond. The latter is typically the dominant effect and so a primary allylic carbocation with a trisubstituted double bond is more stable than a tertiary allylic carbocation with a monosubstituted double bond. Electrophilic addition to a conjugated diene is temperature dependent where reaction at or below room temperature typically leads to a mixture of products in which the 1,2 adduct (or direct addition product) predominates, this is termed kinetic control. At elevated temperatures the reactions have time to come to equilibrium and typically the 1,4 adduct (or conjugate addition product) will predominate, this is termed thermodynamic control. Draw curved arrows to show the movement of electrons in this step of the mechanism.
Answer:
Check the explanation
Explanation:
Kindly check the attached image below for the step by step explanation to the question above.
Footballs used by the NFL are inflated to 12.5 psi. 11 of 12 footballs measured 10.5 psi after the playoff game when the temperature was 5°C. At what temperature were the balls inflated to explain this pressure drop?
Final answer:
After calculating T1, we will have our answer in Kelvin, which can be converted back to degrees Celsius by subtracting 273.15.
Explanation:
To determine at what temperature the NFL footballs were inflated before the pressure dropped to 10.5 psi from 12.5 psi, we can use the ideal gas law and assume that the volume of the footballs remains constant (since they're made of materials that don't expand or contract much with temperature). The ideal gas law implies a direct relationship between pressure and temperature, meaning that if the temperature drops, the pressure will also drop, provided the number of moles of gas and the volume remain constant.
Starting with the initial condition, where P1 = 12.5 psi and the final condition where P2 = 10.5 psi at T2 = 5°C, we can find the initial temperature (T1) using the following relation from Charles's Law:
P1/T1 = P2/T2
However, to use this formula, we need to convert the temperatures into Kelvin:
T1 = (12.5 psi × 278.15 K) / 10.5 psi
After calculating T1, we will have our answer in Kelvin, which can be converted back to degrees Celsius by subtracting 273.15.